Subject: XRD Application using 2D-SAXS_WAXS system

The Bridge | Materials Analysis eNewsletter

FEBRUARY 2020, ISSUE 80

WELCOME

2020 will be a busy year for Rigaku with many events already scheduled across the globe.


The new year also brings a new look to The Bridge! The new design is optimized for easy mobile and tablet viewing.


This month's Rigaku Journal discusses the basic principle and operation methods of the direct-derivation method. Featured in this issue is a report on last month's Conference of the Asian Crystallographic Association (AsCA 2019), at which Rigaku presented an informative workshop on the latest techniques in single crystal and powder diffraction.


This month's issue also contains application notes for XRD, XRF, and EDXRF. The XRD application note discusses the crystallization of chocolate obtained under several tempering speeds observed by simultaneous XRD-DSC measurement. In the XRF Application Note, Rigaku introduces the GEO-TRACE-PAK and demonstrates analysis results of trace elements in geological samples using this analysis package. The EDXRF application note covers the analysis of air filters and compliance with instrument sensitivity as outlined by U.S. EPA method IO-3.3.


A collection of news reports presenting the latest developments in materials science is also included at the bottom of the page.


Enjoy!

UPCOMING RIGAKU EVENTS

Booth 4725

Chicago, IL

March 1-5, 2020


Booth 166

Dubai, UAE

March 16-18, 2020


Booth 431

Munich, Germany

March 31-April 3, 2020

FEATURED JOURNALS & REPORTS

Evaluation of crystalline polymer materials using a 2D-SAXS/WAXS system

By Yukiko Namatame & Keigo Nagao, Rigaku Corporation


In a crystal, atoms or molecules are arranged in a three-dimensional, repetitive pattern, and the properties of the crystal are determined by the chemical composition of the constituent atoms or molecules. The typical image of a crystal is a grain of a single crystal such as salt or alum, but many familiar materials, such as metals, ceramics, and crystalline polymers, are solids composed of microcrystals. These are called polycrystals, in contrast to single crystals.

FEATURED PRODUCTS

Rigaku NANOPIX mini

AutoMATE II


Residual stress may be created during the manufacturing process of a material, or it may accumulate in a structure over many years in operation. In either case, this stress can have a serious negative effect on a product's quality, durability and lifetime. Accurate detection of residual stress is an important element of the quality control process and helps predict the service lifetime of products.

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Rigaku ZSX Primus IV

SmartLab®


Rigaku SmartLab® is the newest and most novel high-resolution X-ray diffractometer (XRD) available today. Perhaps its most novel feature is the new SmartLab Studio II software, which provides the user with an intelligent User Guidance expert system functionality that guides the operator through the intricacies of each experiment. It is like having an expert standing by your side.

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FEATURED APPLICATION NOTES

Evaluation of Stress Distribution in the Depth Direction of a Spring by Micro Area XRD

Rigaku Corporation


Shot peening is a surface treatment method mainly used to improve the durability and reliability of metal parts. Materials such as iron and ceramics are shot at the surface of metal parts at high speed to create compressive residual stress, which improves fatigue strength and durability against stress corrosion. Shot peening is applied, for example, to metal parts on aircraft and automobiles, pressure vessels in chemical plants, etc., which are used continuously for a long time.

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Fused Bead Analysis for Wide Concentration Ranges of Various Oxide Materials Using OXIDE-FB-PAK

Rigaku Corporation


The fusion method in X-ray fluorescence (XRF) analysis is an effective sample preparation technique for getting accurate analysis results of powder samples, since the technique eliminates heterogeneity due to grain size and mineralogical difference. In addition, the homogenization of material property by vitrification makes it possible to expand the calibration range by the use of synthetic standards of fused beads with reagents or by using diverse reference materials.

Rigaku provides an analysis package for various oxide materials by the fusion method, named "OXIDE-FB-PAK".

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Nuclear Power Station Cooling Water Filters

Applied Rigaku Technologies


Excessive metal content can contribute to corrosion in the piping used in the cooling systems in power stations. Corrosion is minimized by the selection of metal alloys used for the pipes and the chemistry of the cooling water itself. The cooling water is monitored for excessive metal content using both Millipore and Cation filters. The filters are then analyzed to determine concentrations of Fe and Cu, as well as other unwanted metals such as Ni, Zn and Pb. To meet the analytical demands of the industry Applied Rigaku technologies offers the NEX DE EDXRF analyzer.

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FEATURED VIDEO & USEFUL LINK OF THE MONTH

Rigaku CT Webinar: X-ray Computed Tomography for Materials Science 1: Introduction


An introduction to the X-ray computed tomography (CT) technique. Designed to show how X-ray CT works and how it can be applied to scientific research. It will include an introduction to the technique, instrumentation and application examples.

MatWeb

Search MatWeb for Property Information


MatWeb's searchable database of material properties includes data sheets of thermoplastic and thermoset polymers such as ABS, nylon, polycarbonate, polyester, polyethylene and polypropylene; metals such as aluminum, cobalt, copper, lead, magnesium, nickel, steel, superalloys, titanium and zinc alloys; ceramics; plus semiconductors, fibers, and other engineering materials.

MATERIAL ANALYSIS IN THE NEWS

February 3, 2020: Scientists from the University of Bristol and Université Paris-Saclay have discovered a new class of material—non-sticky gels. Until now gels have been made of particles that stick to one another to form a network. The research team, whose findings are published in the journal Proceedings of the National Academy of Sciences, have now shown that networks can from and persist without the particles sticking to one another if the particles behave as liquid crystals.


February 3, 2020: A new electrode design may lead to more powerful batteries. New research by engineers at MIT and elsewhere could lead to batteries that can pack more power per pound and last longer, based on the long-sought goal of using pure lithium metal as one of the battery's two electrodes, the anode. The new electrode concept comes from the laboratory of Ju Li, the Battelle Energy Alliance Professor of Nuclear Science and Engineering and professor of materials science and engineering.


February 4, 2020: University of Chicago scientists have created a tough material able to stretch, heal and defend itself – a synthetic tissue that can much more closely mimic biological skin and tissue than existing technology can.


February 5, 2020: 3-D printers working in the millimeter range and larger are increasingly used in industrial production processes. Many applications, however, require precise printing on the micrometer scale at a far higher speed. Researchers of Karlsruhe Institute of Technology (KIT) have developed a system to print highly precise, centimeter-sized objects with submicrometer details at a so far unmatched speed.


February 5, 2020: In Massachusetts, a scientist is preparing to take tricorders to Mars. Star Trek’s Tricorder technology may have been a fantasy in the 1960s, but the instruments used to analyze, identify and record data have been manufactured for commercial use since the 1980s. Mount Holyoke College Kennedy-Schelkunoff Professor of Astronomy Darby Dyar wants to perfect how those instruments identify materials in outer space.


February 7, 2020: A new reaction system can detect X-rays at the highest sensitivity ever recorded by using organic molecules. The system, developed by researchers at Nara Institute of Science and Technology (NAIST), Ikoma, Japan; and Centre National de la Recherche Scientfique (CNRS), Toulouse, France, involves the cycloreversion of terarylene, causing the molecule to switch reversibly between colorless and blue isoforms in the presence or absence of X-rays.


February 7, 2020: Employing X-ray tomography at the European Synchrotron Radiation Facility (ESRF) in Grenoble, international team of researchers were able to use neutrons and X-rays to analyze the aging of lithium batteries and detect deformations and discontinuities that develop during the charging cycles.


February 10, 2020: Rutgers biomedical engineers have developed a "bio-ink" for 3-D printed materials that could serve as scaffolds for growing human tissues to repair or replace damaged ones in the body.


February 7, 2020: Researchers Find New Way to Analyze Chemistry of Lunar Soil. An international team of planetary scientists and geochemists from the United States and Switzerland has demonstrated that a technique called atom probe tomography can be successfully used to characterize the composition and texture of single grains of lunar dust at near-atomic resolution.


February 10, 2020: Biomedical engineers from Rutgers University have developed a 3D printing system would print gel scaffolds, or support structures, for growing human tissues to repair or replace damaged ones in the body.


February 13, 2020: The fastest way to heat certain materials may be to cool them first. A theoretical study suggests the counterintuitive idea that the fastest way to heat specific types of materials may be by cooling them first. The idea parallels the Mpemba effect, in which hot water sometimes freezes faster than cold


February 13, 2020: A new process for preserving lumber could offer advantages over pressure treating. Researchers at the Georgia Institute of Technology have developed a new method, using atomic layer deposition, that could one day replace conventional pressure treating of wood as a way to make lumber not only fungal-resistant but also nearly impervious to water—and more thermally insulating.


February 14, 2020: Quantum interference observed in real time: Extreme UV-light spectroscopy technique. A team from the Institute of Physics at the University of Freiburg has succeeded in observing in real-time ultrafast quantum interferences—in other words the oscillation patterns—of electrons which are found in the atomic shells of rare gas atoms.


February 18, 2020: Researchers report on helical soft-X-ray beams. In a paper published on Friday, 14 February, Advanced Research Center for Nanolithography (ARCNL) researchers Lars Loetgering and Stefan Witte, together with colleagues from Germany and the U.S., reported on a method that enables the generation of soft X-ray beams with controlled orbital angular momentum (OAM).


February 19, 2020: Synthesizing useful organic compounds has now been made easier and cheaper. The Suzuki-Miyaura reaction is a well-known chemical process in which a reaction between organic boronic acids and aryl halides leads to the synthesis of "biaryl" compounds, which are important components of various drugs and chemical products. In a new study published in ACS Catalysts, a team of scientists from Japan, has shown how this reaction can be made more efficient.


February 14, 2020: Quantum interference was observed in real time using an extreme UV-light spectroscopy technique. A team from the Institute of Physics at the University of Freiburg has succeeded in observing in real-time ultrafast quantum interferences—in other words the oscillation patterns—of electrons which are found in the atomic shells of rare gas atoms.


February 18, 2020: Researchers recently developed a technique that can be used to build carbon-nanotube-based fibers by creating chemical crosslinks; the technique improves the electrical and mechanical properties of these materials.


February 18, 2020: A Researcher's use of crystal X-ray diffraction could change wastewater treatment. Concordia graduate student Victor Quezada aims to dramatically reduce our exposure to contaminants like pharmaceuticals and personal-care products. His research focuses on metal-organic frameworks that, with proper synthesis, could act as absorbents that remove the low-level contaminants missed by traditional treatment programs.


February 19, 2020: A real-world experiment achieved quantum entanglement across 52-mile fiber network. Scientists from Argonne National Laboratory and the University of Chicago entangled photons across a 52-mile network in the Chicago suburbs, an important step in developing a national quantum internet.


February 20, 2020: A team of researchers in Sweden has developed a new bioplastic that, unlike traditional carbon-based plastics or other bioplastics, provides protection from the ultraviolet (UV) radiation. The researchers developed a biomass-based copolymer whose bisfuran structure was found to effectively prevent UV radiation from passing through a film made from the material.


February 20, 2020: The US FDA is considering whether to extend the reporting of asbestos in talc to all elongate mineral particles (EMP) with the same composition and crystal structure, according to a document currently undergoing public review. The report was written by the Interagency Working Group on Asbestos in Consumer Products (IWGACP) and published by the FDA.


February 21, 2020: Japanese space agency JAXA is gearing up for an ambitious unmanned space expedition to explore Phobos, one of the two moons that orbit Mars. A probe will orbit and survey both of Mars's moons, while a rover tasked with collecting samples alongside other scientific experiments will land on Phobos. If all goes well, the spacecraft will return to Earth in with the soil samples.


February 21, 2020: In manufacturing, controlling the three-dimensional shapes of macrocycles is critical. In a newly published study, a University of Montreal team led by chemistry professor Shawn Collins reports that they have succeeded in using a natural process called biocatalysis to control the shapes of macrocycles, which is said could be a boon for the making of pharmaceuticals and electronics.

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